PFAS Problems

 

In the interest of full disclosure, I’m about to take on a topic that can be incredibly boring and try to make it endlessly fascinating. There’s no guarantee I’m going to succeed, but we’ve all heard the famous quote, “Shoot for the moon. Even if you miss, you’ll land among the stars.” Or, if you miss really badly, crash through the earth’s atmosphere and die a horrible death as you land on some parking lot in Topeka. I’m sure that’s not going to happen.

This past week, the EPA made news. Or they tried to and mostly failed, I think. They issued a press release on new drinking water standards for PFAS chemicals. More on what those are in a bit, but I was particularly impressed with the press release itself. The statement had more high fives and self-congratulation than a college basketball game. In addition to quoting the President and the EPA director, it quoted a number of politicians. And then there was this hidden gem in the middle of the statement:

“After decades of delay, President Biden’s EPA has delivered a drinking water standard for PFOA and PFOS which, when finalized, will be the toughest in the nation,” said activist and actor Mark Ruffalo. “By proposing to regulate four other PFAS as a mixture, the Biden EPA is also putting our communities ahead of the polluters. President Biden and his team pledged to make PFAS a priority and he has delivered. No Administration has done more to address the urgent threat posed by these toxic forever chemicals than the Biden Administration. My message to polluters is simple: after poisoning your workers and neighbors for decades, it is time to make our public health, not your profits, our top priority. My message to communities devastated by PFAS pollution is equally simple: help is finally on the way.”

That’s a direct quote from noted environmental scientist Mark Ruffalo. I’d tell him he needs to stay in his lane, but then he’d just turn into the hulk and beat me senseless, so I think I’ll pass. Do you know what wasn’t in the press release? Quotes from actual environmental scientists or links to studies about PFAS. As an environmental engineer, I was hoping for more.

Now I need to step back and do some explaining. PFAS stands for per- and polyfluoroalkyl substances. It’s a family of man-made chemicals that can do some pretty amazing things. PFAS chemicals are what make your no-stick pan surfaces no-stick. PFAS chemicals are key ingredients in dental floss and some deodorants and a whole host of other household goods. They are ubiquitous in your home and on the job and at the grocery store. The wrapper the fast food joint just wrapped your burger in may have a PFAS chemical.

So does that mean you need to make a trip to your trash bin with a whole bunch of household goods that you previously thought you couldn’t live without? Well, no. Or maybe I should say, probably not. These chemicals have been around now for 80 years or so and we’ve only spent the last 25 years or so doing the research, although it appears that DuPont started getting concerned about their money machine in the ’70s and started doing their own research. Some of these chemicals are currently thought to be safe. Some of them we are pretty sure are a problem. To date, no one has proven that any of them are actually dangerous, but the research continues. The EPA press release focused on two chemicals in particular, PFOS and PFOA (I won’t bore you with what these actually stand for) and four other chemicals that are also being limited, although how they are being limited is a little less clear. The health concern is all over the map. Possible cancers, infertility, kidney problems… the list of potential concerns is quite long.

Those two particular chemicals are in a few household products, like Scotchgard and floor wax, but they are most prevalent in the environment through their use as a fire suppressant. The chemicals are surfactants, which for firefighting purposes, means that if you shoot them through a nozzle they form a foamy substance that smothers fires. These are particularly useful for large fuel fires like what you get when your extremely expensive military aircraft catches fire. As you can imagine, they are particularly useful at airports or Air Force bases and many bases in the other services used them as well. For this purpose, they worked great, but military brass can read the handwriting on the wall as well as the next guy and their use in the military has now been banned. The math calculation was simple. We can either save our aircraft worth hundreds of millions of dollars or we can let it burn and avoid the lawsuit. It was an easy choice.

Nonetheless, this surfactant, called AFFF (aqueous film forming foam, if you’re interested), has been used for forty years now and it is found in groundwater and stormwater near most of these installations and airports. If you watch late-night television, I’m sure you are familiar with AFFF, as legal firms across the country are jumping in on the potential gravy train. Incidentally, I find myself irrationally irritated by how these commercials pronounce AFFF. They all pronounce it “A-eff-eff-eff.” Before these ads, I’d never heard it pronounced as anything other than “A-triple-eff.” If they are shooting for the golden payout, at least they could at least get their nomenclature right.

EPA has been struggling with how to regulate PFAS chemicals for nearly a decade. Around five years ago, EPA finally arrived at a not particularly scientifically relevant lifetime health advisory of 70 parts per trillion in drinking water. That’s a very small number. Let’s say you’ve got a standard-size swimming pool in your backyard and you want to put 70 parts per trillion of PFAS in the pool. You’ll need to put in about 0.003 milliliters of PFAS in your pool, or considerably less than one droplet. That’s a difficult standard and it didn’t really have a scientific basis, but for those of us trying to deal with the crisis, at least we finally had something tangible to work with. We could start figuring out how to clean up the mess.

For many environmental groups, a few of which believe that PFAS is horribly toxic at any level, that was not nearly good enough and some were stating that the limit should be zero. They found a sympathetic ear in Joe Biden’s EPA, which led to the announcement in the press release. The new limits are at 4 parts per trillion which, as it happens, is exactly the lowest we can measure. The EPA has essentially set the limit at zero. It could have been worse. Originally, they were pushing for a limit in the lower parts per quadrillion.

So what can be done? One of the biggest selling points for PFAS chemicals was that they never wear out or break down, which is why environmental groups like to call them (not inaccurately, I might add) “forever chemicals.” Now, that characteristic is understood as a serious roadblock to their elimination from contaminated water supplies. You can’t readily break them down into harmless constituents. They also easily mix with water, making them even more difficult to remove and nearly impossible to contain. Getting them out of contaminated water supplies is going to be very difficult and very expensive, when it can be done at all. The systems currently on the market to treat contaminated water are nearly the same ones they use to remove radioactive contaminants from cooling water in nuclear reactors. That works okay when you’re treating a few thousand gallons of purified water, but it’s quite another to take the chemicals out of a drinking water well or a lake. In other words, if you have any good ideas about how to treat for PFAS contamination, you are about to become extremely wealthy. Sadly, I am not going to become extremely wealthy.

The takeaway from all of this is that the EPA announcement is going to have a huge impact for your life, far more than the publicity it got. And it’s going to have an impact even if you aren’t living near a military base or fire station.

And as for making this post interesting, I think I just heard a loud thud coming from Topeka.

Published in Environment
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There are 9 comments.

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  1. MarciN Member
    MarciN
    @MarciN

    Great post. Important information. We have lost three of our thirty wells in our town to these relatively benign chemicals, which as you’ve said, have been around for at least eighty years. It’s very frustrating.

    • #1
  2. Charlotte Member
    Charlotte
    @Charlotte

    I wish there were some way to quantify and then (as important) clearly communicate exactly how much these obscure regulations (of which this is only one of, presumably, many thousands) are costing every single American household annually.

    Many thanks for the terrific post. 

    • #2
  3. EODmom Coolidge
    EODmom
    @EODmom

    Maybe finally Solution can say it’s found its Problem. The sound you hear is Topeka cheering. And Shawnee too. 

    • #3
  4. ctlaw Coolidge
    ctlaw
    @ctlaw

    Aren’t these chemicals what are known as “gender benders”? If so, imagine Biden going off on one of his rambling speeches about that particular effect of the chemicals on modern society.

    https://www.dailymail.co.uk/femail/food/article-1245151/Killers-kitchen-Gender-bending-packaging-exploding-floor-cleaners-toasters-deadly-sharks-.html

    • #4
  5. Mark Camp Member
    Mark Camp
    @MarkCamp

    This morning, the Ricochet newsboy delivers to our doorstep two very fine articles in two different sections.  The Cultural History one (McVey) and now, in the late morning edition of the newspaper: the Public Health and Safety page.

    Or is it the War news? Religious War news, maybe?  Anyway, the news from the front continues to be dismal when it come to the proggy campaign to save us from our public health emergency–the existence of chemicals–and thereby annihilate our racist civilization.

    At this point, we’d be better off to cut our losses and negotiate a political compromise with the proggers:

    Concession by the radical left: They will end hostilities and withdraw their zealous bureaucratic battalions from our territory. (The United States of America within its pre-war boundaries.)

    Concessions by us, the Americans: They will be allowed to put all of their troops to work printing up labels…

    Warning: This world contains chemicals. Chemicals are known to the State of California to cause cancer.

    …and gluing them to everything, subject to the following restriction: the glue must contain less that 1 part per quadrillion of chemicals.

    • #5
  6. The Reticulator Member
    The Reticulator
    @TheReticulator

    Will there be 10 percent for the big guy on any remediation spending? Or for his party, at least? 

    • #6
  7. Hang On Member
    Hang On
    @HangOn

    One source of PFAS and PFOAS is the manufacturing plants. This is a huge problem in North Carolina where I live. There is a plant in Fayetteville, NC and it has polluted all the waters downstream in the Cape Fear Basin. Wilmington, NC is downstream. 

    The PFAS and PFOAS came out the smoke stack at the factory as they were burned, but then the EPA and the NC Dept of Environment and Natural Resources signed an agreement that the air from the smokestack would be washed, but no further monitoring of the water nor water treatment would be required. Neither PFAS nor PFOAS was placed on the list for water treatment plants nor for land application of the residuals from wastewater treatment plants was required.

    Detlef Knappe is a friend and colleague who has done lots of work on this. Here is a list of articles he has published on the problem.  

    • #7
  8. David Pettus Coolidge
    David Pettus
    @DavidPettus

    The Reticulator (View Comment):

    Will there be 10 percent for the big guy on any remediation spending? Or for his party, at least?

    I wouldn’t bet against it.

    • #8
  9. Mark Camp Member
    Mark Camp
    @MarkCamp

    Hang On (View Comment):

    One source of PFAS and PFOAS is the manufacturing plants. This is a huge problem in North Carolina where I live.

    Is there any scientific evidence indicating that it is a huge problem?

    If not, that may be the reason, or part of the reason, that the remedies you mention have not been applied.

    • #9
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